Isoprene chain shuttling polymerisation between cis and trans regulating catalysts: straightforward access to a new material.
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DOI: 10.1039/c7cc01016h
Abstract: Isoprene chain shuttling polymerisation between the 1,4-trans regulating Cp*La(BH4)2(THF)2/MgnBuEt (Cp* = C5Me5) and the 1,4-cis regulating NdCl3(THF)2/AlR3 (R = Et or iBu) systems provides access to stereoblock polyisoprene. Under selected experimental conditions, the trans segments… read more here.
Keywords: shuttling polymerisation; trans regulating; chain shuttling; isoprene chain ... See more keywords