Cooperative spin transition in a 1D-polymeric complex [Fe(4-ethyl-1,2,4-triazole)3]SiF6·nH2O
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DOI: 10.1016/j.ica.2020.119560
Abstract: Abstract A new 1D-polymeric iron(II)-1,2,4-triazole complex, [Fe(EtTrz)3]SiF6·nH2O (EtTrz = 4-ethyl-1,2,4-triazole, n = 1, 0), demonstrates cooperative spin transition above room temperature. Under vacuum the complex loses its water molecules and shows an abrupt and reproducible spin transition with thermal… read more here.
Keywords: spin transition; spin; triazole; sif6 nh2o ... See more keywords