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Recent Applications of Ammonium Ylide Based [2,3]-Sigmatropic and [1,2]-Stevens Rearrangements To Transform Amines into Natural Products

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Published in 2023 at "Synthesis"

DOI: 10.1055/s-0042-1751446

Abstract: Ammonium ylide based [2,3]-sigmatropic and [1,2]-Stevens rearrangements enable the transformation of tertiary amines into rearranged and functionalized intermediates en route to many polycyclic natural product targets. Herein, we summarize recent applications of these rearrangement reactions… read more here.

Keywords: sigmatropic stevens; ammonium ylide; based sigmatropic; ylide based ... See more keywords