Metal-free visible-light-mediated aerobic oxidation of silanes to silanols
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DOI: 10.1007/s11426-018-9289-9
Abstract: Oxidation of silanes into silanols using water/air has attracted considerable attention. The known methods with no exception required a metal catalyst. Herein we report the first metal-free method: 2 mol% Rose Bengal as the catalyst,… read more here.
Keywords: oxidation silanes; visible light; silanes silanols; free visible ... See more keywords
Selective oxidation of silanes into silanols with water using [MnBr(CO)5] as a precatalyst
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DOI: 10.1039/d2sc05959b
Abstract: The development of earth-abundant catalysts for the selective conversion of silanes to silanols with water as an oxidant generating valuable hydrogen as the only by-product continues to be a challenge. Here, we demonstrate that [MnBr(CO)5]… read more here.
Keywords: precatalyst; oxidation silanes; selective oxidation; silanes silanols ... See more keywords