Synthesis and Characterization of Yttrium Methanediide Silanide Complexes
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DOI: 10.1021/acs.inorgchem.2c03053
Abstract: The salt metathesis reactions of the yttrium methanediide iodide complex [Y(BIPM)(I)(THF)2] (BIPM = {C(PPh2NSiMe3)2}) with the group 1 silanide ligand-transfer reagents MSiR3 (M = Na, R3 = tBu2Me or tBu3; M = K, R3 =… read more here.
Keywords: thf; methanediide silanide; yttrium methanediide; bipm ... See more keywords
Comparison of group 4 and thorium M(IV) substituted cyclopentadienyl silanide complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00987d
Abstract: We report the synthesis and characterisation of a series of M(iv) substituted cyclopentadienyl hypersilanide complexes of the general formula [M(CpR)2{Si(SiMe3)3}(X)] (M = Hf, Th; CpR = Cp′, {C5H4(SiMe3)} or Cp′′, {C5H3(SiMe3)2-1,3}; X = Cl, C3H5).… read more here.
Keywords: substituted cyclopentadienyl; spectroscopy; comparison group; sime3 ... See more keywords