Copper(II) Ion Promoted Reverse Solvatochromic Response of the Silatrane Probe to Spectral Shifts: Preferential Solvation and Computational Approach.
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DOI: 10.1021/acs.inorgchem.2c02184
Abstract: The unique solvatochromic attitude of an analyte owing to its coordination with metal ions in solvents of different polarities is challenging. Herein, we introduce two new solvatochromic 4-(pentan-3-yl) benzaldehyde-based triazolyl silatrane probes (5 and 6).… read more here.
Keywords: silatrane; mecn meoh; solvation; approach ... See more keywords
Selective mercury ion recognition using a methyl red (MR) based silatrane sensor
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DOI: 10.1039/c8nj00728d
Abstract: A new methyl red (MR) based silatrane was synthesized in high yield by the transesterification reaction of methyl red-amidopropyltrimethoxysilane 1 (MR-APTMS) and trisisopropanolamine. Single crystal X-ray diffraction analysis was used to deduce the structure of… read more here.
Keywords: methyl red; recognition; silatrane; selective mercury ... See more keywords
Synthesis of Silatrane-Containing Organic Sensitizers as Precursors for the Silyloxyl Anchoring Group in Dye-Sensitized Solar Cells
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DOI: 10.1055/s-0036-1588836
Abstract: A series of organic D-Ï€-A dyes, endowed with different silicon-based anchoring groups, has been prepared to assess the stability of such anchoring moieties on nanocrystalline TiO 2 in dye-sensitized solar cells. Due to the difficulties… read more here.
Keywords: dye sensitized; sensitized solar; group; silatrane ... See more keywords
Chemical Attachment of 5-Nitrosalicylaldimine Motif to Silatrane Resulting in an Organic–Inorganic Structure with High Medicinal Significance
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DOI: 10.3390/pharmaceutics14122838
Abstract: Two chemical motifs of interest for medicinal chemistry, silatrane as 1-(3-aminopropyl) silatrane (SIL M), and nitro group attached in position 5 to salicylaldehyde, are coupled in a new structure, 1-(3-{[(2-hydroxy-5-nitrophenyl)methylidene]amino}propyl)silatrane (SIL-BS), through an azomethine moiety,… read more here.
Keywords: structure; silatrane; nitrosalicylaldimine motif; sil ... See more keywords