Silicon-assisted synthesis of new aminomethylenebisphosphonic acids with quinolines moieties
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DOI: 10.1016/j.jorganchem.2020.121286
Abstract: Abstract The convenient silicon-assisted synthesis of new aminomethylenebisphosphonic acids and their precursors was developed via unique methodology. So new aminomethylenebisphosphonic acids with quinolines moieties were obtained using suitable reaction of tris(trimethylsilyl) phosphite and N-formyl aminoquinolines… read more here.
Keywords: synthesis new; silicon assisted; aminomethylenebisphosphonic acids; new aminomethylenebisphosphonic ... See more keywords
Silicon-Assisted Photocatalyzed C-O Bond Cleavage: Broader Applications and Mechanistic Investigations.
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DOI: 10.1021/acs.orglett.5c02502
Abstract: A silicon-assisted C-O bond fragmentation strategy is developed by employing photoredox catalysis. This method describes an efficient transformative alternative for the dealkylation of aryl alkyl ethers comprising bioactive moieties. The protocol was successfully applied to… read more here.
Keywords: mechanistic investigations; bond cleavage; assisted photocatalyzed; silicon assisted ... See more keywords
Silicon-Assisted Ferrier Rearrangement in Preparation of C3-Silyl Glycosides.
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DOI: 10.1021/acs.orglett.5c04215
Abstract: Herein, we report a Lewis acid catalyzed Ferrier rearrangement glycosylation strategy using the α-effect of C3-silylated glucal donors. The dimethylphenylsilyl group at the C3 position promotes the reaction where the unactivated free hydroxy group at… read more here.
Keywords: assisted ferrier; silyl glycosides; silicon assisted; ferrier rearrangement ... See more keywords