Silicon Carbamates by CO2 Fixation: Brønsted Acid Labile Precursor of a Lewis Superacid.
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DOI: 10.1021/acs.inorgchem.2c02754
Abstract: Treatment of Lewis superacidic Si(catCl)2(MeCN)2 and tetramethylpiperidine (TMP) or hexahydropyrimidopyrimidine (hppH) with CO2 leads to an FLP-type formation of silicon carbamates. The employed Lewis base determines the hapticity at silicon and the reactivity of the… read more here.
Keywords: silicon carbamates; co2 fixation; nsted acid; lewis ... See more keywords