Theoretically predicted divalent silicon(0) compounds: Structures and chemical bonding of silylone in molybdenum pentacarbonyl complexes [Mo(CO)5-Si(XCp∗)2] (X = B–Tl)
Sign Up to like & getrecommendations! Published in 2018 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2018.03.021
Abstract: Abstract Quantum chemical calculations of structures and bonding in the transition metal complexes with silylone ligands [Mo(CO)5-Si(XCp∗)2] (Mo5-SiX) (X = B–Tl) are reported at the BP86 level of theory with various basis sets SVP, TZVPP, TZ2P + . The… read more here.
Keywords: predicted divalent; theoretically predicted; silylone; divalent silicon ... See more keywords
Pentacoordinate silicon compounds based on 2,2′-dihydroxyazobenzene ligand
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.120997
Abstract: Abstract The preparation and structures of 6,6-diorganylbenzo[d,h][1,3,6,7,2]dioxadiazasilonines containing the N→Si intramolecular dative bond are described. The complexes were characterized by NMR (1H, 13C, 29Si), IR and UV spectra. The crystal structures of 6-methyl-6-phenyl- and 6-(chloromethyl)-6-methylbenzo[d,h][1,3,6,7,2]dioxadiazasilonines… read more here.
Keywords: pentacoordinate silicon; chemistry; compounds based; based dihydroxyazobenzene ... See more keywords
Complementary bonding analysis of the N-Si interaction in pentacoordinated silicon compounds using quantum crystallography.
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DOI: 10.1039/c9dt02772f
Abstract: The N-Si interaction in two pentacoordinated silicon compounds is investigated based on a complementary bonding analysis, which consists of bonding descriptors from real space and orbital space. These are derived from X-ray wavefunction refinements of… read more here.
Keywords: bonding analysis; pentacoordinated silicon; interaction; complementary bonding ... See more keywords
Bending Strength of Wood Treated with Propolis Extract and Silicon Compounds
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DOI: 10.3390/ma14040819
Abstract: The modification of wood and its treatment with various preservatives may affect its mechanical properties, hence the knowledge of the character changes in wood caused by impregnation is of great importance. Therefore, the aim of… read more here.
Keywords: wood treated; mptmos teos; impregnation; propolis extract ... See more keywords
The Effects of Foliar Sprays with Different Silicon Compounds
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DOI: 10.3390/plants7020045
Abstract: The use of foliar sprays with silicon compounds is relatively new. Initially (in 1990) foliar sprays with silicates were used. In 2003, foliar sprays with (stabilized) silicic acid were introduced, and more recently foliar sprays… read more here.
Keywords: effects foliar; foliar sprays; sprays different; different silicon ... See more keywords