Articles with "silsesquioxane" as a keyword



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Hydrogen Silsesquioxane‐Based Nanofluidics

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Published in 2017 at "Advanced Materials Interfaces"

DOI: 10.1002/admi.201601155

Abstract: Nanofluidics show great promise for the control of small volumes and single molecules, especially for biological and energy applications. To build up more and more complex nanofluidics systems, a versatile and reproducible fabrication technique with… read more here.

Keywords: hydrogen silsesquioxane; silsesquioxane; based nanofluidics; silsesquioxane based ... See more keywords
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Sulfur-Containing Silsesquioxane Derivatives Obtained by the Thiol-ene Reaction: Synthesis and Thermal Degradation.

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Published in 2022 at "ChemPlusChem"

DOI: 10.1002/cplu.202200099

Abstract: This article presents the synthesis of new derivatives of octa(3-thiopropyl)silsesquioxane (SSQ-8SH) via thiol-ene reaction with simple olefins bearing alkyl groups as well as methoxysilyl, substituted aryl or fluoroalkyl groups. All products were characterized by 1… read more here.

Keywords: ene reaction; silsesquioxane; thiol ene; thermal degradation ... See more keywords
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Synthesis and Steady State Photophysical Property Analysis of Beads on a Chain (BoC) Silsesquioxane Oligomers Containing Arene and Heteroarene Cross-linkers

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Published in 2021 at "Silicon"

DOI: 10.1007/s12633-021-01179-0

Abstract: Silsesquioxane-based materials are garnering considerable attention due to their unique structural and electronic properties which enable use in diverse fields of study. In this article, we investigate a series of hybrid oligomeric materials comprising a… read more here.

Keywords: silsesquioxane; cross linkers; cross; steady state ... See more keywords
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Autonomous Bionanorobots via a Cage-Shaped Silsesquioxane Vehicle for In Vivo Heavy Metal Detoxification.

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Published in 2022 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.2c05736

Abstract: Nanorobots hold great promise for integrated drug delivery systems that are responsive to molecular triggers. Herein, we successfully developed an automatic smart bionanorobot that has transport capability and recognizes and removes zinc ions from poisoned… read more here.

Keywords: cell; zinc ions; bionanorobots via; autonomous bionanorobots ... See more keywords
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Sulfonic Acid-Grafted Hybrid Porous Polymer Based on Double-Decker Silsesquioxane as Highly Efficient Acidic Heterogeneous Catalysts for the Alcoholysis of Styrene Oxide.

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Published in 2023 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.2c17732

Abstract: β-Alkoxyalcohols generated from epoxide ring-opening reactions are significant due to their enormous value as pharmaceutical intermediates and fine chemicals. Using a phenyl-substituted double-decker-type silsesquioxane as the precursor, a hybrid porous material (PCS-DDSQ) was synthesized through… read more here.

Keywords: double decker; spectroscopy; so3h; styrene oxide ... See more keywords
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Porous Silsesquioxane-Imine Frameworks as Highly Efficient Adsorbents for Cooperative Iodine Capture.

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Published in 2018 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.8b03023

Abstract: The efficient capture and storage of radioactive iodine (129I or 131I), which can be formed during nuclear energy generation or nuclear waste storage, is of paramount importance. Herein, we present highly efficient aerogels for reversible… read more here.

Keywords: silsesquioxane; silsesquioxane imine; porous silsesquioxane; iodine capture ... See more keywords
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Effect of Shear Stress during Processing on Structure, Morphology, and Properties of Isotactic Polypropylene Nucleated with Silsesquioxane-Based β-Nucleating Agent

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Published in 2023 at "Materials"

DOI: 10.3390/ma16103627

Abstract: The study aimed to determine the influence of shear stress during real-life industrial processes such as compression molding and injection molding to different cavities on the crystallization of the isotactic polypropylene nucleated with a novel… read more here.

Keywords: nucleating agent; polypropylene nucleated; isotactic polypropylene; silsesquioxane based ... See more keywords
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Thiolated Janus Silsesquioxane Tetrapod: New Precursors for Functional Materials

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Published in 2022 at "Molecules"

DOI: 10.3390/molecules27227680

Abstract: Herein, we report synthetic strategies for the development of a bifunctional Janus T4 tetrapod (Janus ring), in which the orthogonal silsesquioxane and organic faces are independently functionalized. An all-cis T4 tetrasilanolate was functionalized to introduce… read more here.

Keywords: thiolated janus; silsesquioxane tetrapod; janus; silsesquioxane ... See more keywords
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Synthesis of metallo-supramolecular materials based on terpyridine functionalized double-decker silsesquioxane with improved complexation efficiency

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Published in 2020 at "Turkish Journal of Chemistry"

DOI: 10.3906/kim-1909-60

Abstract: Silsesquioxane-based transition-metal complexes have come to the forefront due to the ability of silsesquioxane to control nanostructures and properties. However, some difficulties in complete complexation and purification limit the widespread use of transition-metal-based supramolecular coordination… read more here.

Keywords: silsesquioxane; metallo supramolecular; complexation; synthesis metallo ... See more keywords