Metallophilic interactions in silver(I) dicyanoaurate complexes.
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DOI: 10.1039/d2dt00615d
Abstract: This manuscript reports four new gold(I)-silver(I) complexes with 2-(2-pyridyl)-1,8-naphthyridine (pyNP) and terpyridine (terpy) as ancillary ligands, having formulae [Ag(pyNP)(Au(CN)2)]2 (1), [Ag2Au2(μ-CN)2(CN)2(pyNP)2] (2), [Ag2Au(μ-CN)2(terpy)2][Au(CN)2] (3) and [Ag4Au4(μ-CN)8(terpy)2(py)] (4). Complexes 1 and 2 are structural isomers obtained… read more here.
Keywords: metallophilic interactions; chemistry; terpy; silver dicyanoaurate ... See more keywords