Silver(I)-Mediated 2D DNA Nanostructures.
Sign Up to like & getrecommendations! Published in 2024 at "Small"
DOI: 10.1002/smll.202407604
Abstract: Structural DNA nanotechnology enables the self-organization of matter at the nanometer scale, but approaches to expand the inorganic and electrical functionality of these scaffolds remain limited. Developments in nucleic acid metallics have enabled the incorporation… read more here.
Keywords: silver mediated; mediated dna; nanotechnology; dna nanostructures ... See more keywords
Mechanistic insights into silver(I)-mediated trifluoromethylation of aryldiazonium salts
Sign Up to like & getrecommendations! Published in 2019 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2019.04.015
Abstract: Abstract The mechanism of silver(I)-mediated trifluoromethylation of aryldiazonium salts has been studied comprehensively with density functional theory (DFT). Three stages constitute the trifluoromethylation pathway, namely (i) dissociation of the aryldiazonium salt, (ii) formation of the… read more here.
Keywords: trifluoromethylation aryldiazonium; mediated trifluoromethylation; aryldiazonium; trifluoromethylation ... See more keywords
Light-induced formation of silver(I)-mediated base pairs in DNA: Possibilities and limitations
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119856
Abstract: Abstract The applicability of the caged nucleoside CNPP (2′-deoxycytidine bearing an ortho-nitrophenylpropyl group at the exocyclic N4 position) in the light-triggered formation of three silver(I)-mediated base pairs was probed, namely C–Ag(I)–C, Im–Ag(I)–C and P–Ag(I)–C (Im = imidazole… read more here.
Keywords: mediated base; silver mediated; formation; base pairs ... See more keywords
Access to chromone-3-carboxylic acid via silver mediated coupling of 4-hydroxy coumarin and enol ester
Sign Up to like & getrecommendations! Published in 2021 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2021.153206
Abstract: Abstract A silver-mediated aerobic approach to access 2-methyl-chromone-3-carboxylic acid from the reaction of 4-hydroxy coumarin and enol ester in the presence of base has been presented. Mechanistic investigation suggests that the base induced Michael-type addition… read more here.
Keywords: coumarin enol; hydroxy coumarin; enol ester; silver mediated ... See more keywords
transoid and cisoid Conformations in Silver-Mediated Cytosine Base Pairs: Hydrogen Bonding Dictates Argentophilic Interactions in the Solid State.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02228
Abstract: We have synthesized and structurally characterized examples of the well-known silver-mediated DNA base pair in its simplest possible form, as [AgI-bis-(N3-cytosine)]+. The compounds show differences such as variable coordination geometry, conformation with cisoid and transoid… read more here.
Keywords: cisoid; hydrogen; silver mediated; geometry ... See more keywords
Silver-Mediated Acetoxyselenylation of Alkynes: Mild Stereoselective Access to Bifunctional Alkenes.
Sign Up to like & getrecommendations! Published in 2024 at "Organic letters"
DOI: 10.1021/acs.orglett.4c03178
Abstract: Herein, we report a AgF-mediated regio- and stereoselective acetoxyselenylation of terminal/internal alkynes from iodobenzene dicarboxylate [PhI(OCOR)2] and diorganyl diselenides via multiple-site functionalization to afford β-selenyl enol esters in good yields. Alkynes derived from bioactive molecules,… read more here.
Keywords: silver mediated; acetoxyselenylation; mediated acetoxyselenylation; acetoxyselenylation alkynes ... See more keywords
Silver-Mediated Dual Oxidation of 1,3-Dicarbonyls for Migration-Annulation.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c02001
Abstract: A new type of radical cascade reaction has been reported, by which free radicals were generated twice successively through the implementation of dual oxidation on a 1,3-dicarbonyl compound in a single operation, thereby realizing a… read more here.
Keywords: migration; migration annulation; dual oxidation; silver mediated ... See more keywords
Silver-Mediated Direct C-H Cyanation of Terminal Alkynes with N-Isocyanoiminotriphenylphosphorane.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b02743
Abstract: A direct cyanation of terminal alkynes for the synthesis of propionitrile derivatives, with the aid of silver salt using water additive, has been achieved. The cyano source used is N-isocyanoiminotriphenylphosphorane, which is nontoxic, safe, and… read more here.
Keywords: cyanation terminal; silver mediated; terminal alkynes; direct cyanation ... See more keywords
Silver-Mediated Electrosynthesis of Substituted Isoquinolines via Cyclization of 2-Ethynylbenzaldehydes
Sign Up to like & getrecommendations! Published in 2025 at "ACS Omega"
DOI: 10.1021/acsomega.5c08865
Abstract: The electrosynthesis of substituted isoquinolines via silver-mediated intramolecular cyclization of 2-ethynylbenzaldehydes with ammonium acetate is presented. The reaction employs Ag(+)|C(−) electrodes in a DMF/isopropanol mixture at 60 °C using LiClO4 as the supporting electrolyte, affording… read more here.
Keywords: cyclization ethynylbenzaldehydes; silver mediated; electrosynthesis substituted; substituted isoquinolines ... See more keywords
Silver-mediated radical phosphorylation/cyclization of N-allylbenzamides to access phosphoryl-substituted dihydroisoquinolones
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj02833a
Abstract: A silver-mediated phosphorylation/cyclization of N-allylbenzamides with phosphine oxides for the synthesis of phosphoryl-substituted dihydroisoquinolones was developed. read more here.
Keywords: cyclization allylbenzamides; phosphoryl substituted; phosphorylation cyclization; substituted dihydroisoquinolones ... See more keywords
Silver-mediated synthesis of novel 3-CF3/CN/phosphonate-substituted pyrazoles as pyrrolomycin analogues from 3-formylchromones and diazo compounds
Sign Up to like & getrecommendations! Published in 2019 at "Organic Chemistry Frontiers"
DOI: 10.1039/c9qo00324j
Abstract: Herein, a simple and regioselective synthesis of (2-hydroxyphenyl)(3-(trifluoromethyl/cyano/phosphonate)-1H-pyrazol-5-yl)methanones as pyrrolomycin analogues was reported. read more here.
Keywords: synthesis novel; synthesis; silver mediated; pyrrolomycin analogues ... See more keywords