Formal Hydrotrimethylsilylation of Styrenes with Anti-Markovnikov Selectivity Using Hexamethyldisilane.
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DOI: 10.1021/acs.orglett.2c03170
Abstract: A combination of CsF and hexamethyldisilane in DMSO enabling an anti-Markovnikov formal hydrotrimethylsilylation of styrenes is reported. Mechanistic investigations detail the reaction pathways, including in situ generation of a silyl anion, the addition of this… read more here.
Keywords: anti markovnikov; formal hydrotrimethylsilylation; silyl anion; hexamethyldisilane ... See more keywords