Reactions of 1-Alkynes with a Molybdenum-Silyl Complex: Stable σ-Acetylide Complexes Containing a Pentadentate Ligand Comprised of a P2SiP2 Framework
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DOI: 10.1246/cl.190631
Abstract: Reactions of molybdenum-silyl hydrido complex 2 ([MoH3{Si(Ph)[Ph2PCH2CH2P(Ph)C6H4-o]2}]) with 1.5 equiv of 1-alkynes RC≡CH occur readily at room temperature giving σ-acetylide complexes ([MoH2{Si(P... read more here.
Keywords: molybdenum silyl; reactions alkynes; acetylide complexes; silyl complex ... See more keywords