Synthesis of Unsaturated Silyl Heterocycles via an Intramolecular Silyl-Heck Reaction.
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DOI: 10.1021/acs.organomet.9b00498
Abstract: We report the synthesis of unsaturated silacycles via an intramolecular silyl-Heck reaction. Using palladium catalysis, silicon electrophiles tethered to alkenes cyclize to form 5- and 6-membered silicon heterocycles. The effects of alkene substitution and tether… read more here.
Keywords: silyl heck; silyl; via intramolecular; synthesis unsaturated ... See more keywords