Visible-Light-Mediated Radical Silyl-Oximation of Activated Alkenes Using tert-Butyl Nitrite and Silanes.
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DOI: 10.1021/acs.orglett.2c03644
Abstract: A metal-free radical 1,2-difunctionalization of activated alkenes with various silanes and tert-butyl nitrite is reported. The radical cascade occurs by light-promoted homolytic O-NO bond cleavage of tert-butyl nitrite and subsequent hydrogen atom abstraction by the… read more here.
Keywords: tert butyl; activated alkenes; butyl nitrite; silyl oximation ... See more keywords