Copper catalyzed N-formylation of α-silyl-substituted tertiary N-alkylamines by air
Sign Up to like & getrecommendations! Published in 2020 at "Green Chemistry"
DOI: 10.1039/d0gc01242d
Abstract: A site-selective method to prepare N-formyl amines efficiently that relies on the copper(I)-catalyzed oxidation of α-silyl-substituted tertiary N-alkylamines by air at room temperature is described. The oxidative protocol was shown to exhibit excellent functional group… read more here.
Keywords: silyl substituted; copper; air; substituted tertiary ... See more keywords
Identification and characterization of selected silyl substituted silyl anions by liquid injection field desorption ionization mass spectrometry
Sign Up to like & getrecommendations! Published in 2022 at "European Journal of Mass Spectrometry"
DOI: 10.1177/14690667221139720
Abstract: Silyl anions are crucial building blocks in silicon chemistry and are frequently used in organosilicon chemistry. These so-called silanides are negatively charged three-coordinate species, isoelectronic to carbanions. In this contribution, we synthesized already literature known… read more here.
Keywords: mass spectrometry; silyl anions; chemistry; silyl substituted ... See more keywords