Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C-H Bonds.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b00737
Abstract: Several classes of enantioselective silylations of C-H bonds have been reported recently, but little mechanistic data on these processes are available. We report mechanistic studies on the rhodium-catalyzed, enantioselective silylation of aryl C-H bonds. A… read more here.
Keywords: studies rhodium; rhodium catalyzed; silylation aryl; mechanistic studies ... See more keywords
Palladium-Catalyzed Catellani-Type Selective C-H Silylation of Aryl-TT salts
Sign Up to like & getrecommendations! Published in 2025 at "Organic Chemistry Frontiers"
DOI: 10.1039/d4qo02349h
Abstract: A palladium-catalyzed three-component reaction of aryl-thianthrenium salts, norbornene/diphenylacetylene, and hexamethyldisilane has been developed for the assembly of highly functionalized disilanes, in which two C-Si bonds and one C-C bond are... read more here.
Keywords: selective silylation; catalyzed catellani; palladium catalyzed; silylation aryl ... See more keywords