Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst
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DOI: 10.1038/s41467-020-19508-z
Abstract: Unlike the well-reported 1,2-difunctionalization of alkenes that is directed by classic pyridine and imine-containing directing groups, oxo-palladacycle intermediates featuring weak Pd-O coordination have been less demonstrated in C-H activated cascade transformations. Here we report a… read more here.
Keywords: weakly coordinated; quadruple activation; coordinated palladium; silylation borylation ... See more keywords
Advances in silylation and borylation of fluoroarenes and gem-difluoroalkenes via C-F bond cleavage.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc04729a
Abstract: Organoboron and organosilane compounds are widely used in organic synthesis and pharmaceuticals. In addition, the C-F bond functionalization is a useful tool for the construction of carbon-carbon and carbon-heteroatom bonds. In particular, the late-stage functionalization… read more here.
Keywords: borylation fluoroarenes; bond; advances silylation; fluoroarenes gem ... See more keywords