Organoelectrophotocatalytic C-H Silylation of Heteroarenes.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c00144
Abstract: An organoelectrophotocatalytic approach for the C-H silylation of heteroarenes through dehydrogenation cross-coupling with H2 evolution has been developed. The organoelectrophotocatalytic strategy is carried out under a simple and efficient monocatalytic system by employing 9,10-phenanthrenequinone both… read more here.
Keywords: organoelectrophotocatalytic silylation; silylation heteroarenes; silylation;
Photocatalytic C–H silylation of heteroarenes by using trialkylhydrosilanes† †Electronic supplementary information (ESI) available: Tables S1–S6, Scheme S1–S8, Fig. S1–S4, experimental procedures and characterization for all of the new compounds. See DOI: 10.1039/c9sc00046a
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c9sc00046a
Abstract: A distinctive visible light-promoted photocatalytic approach for the C–H silylation of heteroarenes by using trialkylhydrosilanes was developed. read more here.
Keywords: using trialkylhydrosilanes; heteroarenes using; trialkylhydrosilanes electronic; silylation heteroarenes ... See more keywords
Decarboxylative C-H silylation of N-heteroarenes with silanecarboxylic acids.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06380h
Abstract: Established decarboxylative Minisci reactions are limited to aliphatic carboxylic acids, as their analogs, silanecarboxylic acids, have been rarely investigated. Herein, we present a new decarboxylative Minisci-type reaction of N-heteroarenes with silanecarboxylic acids under photo- or… read more here.
Keywords: silanecarboxylic acids; silylation heteroarenes; decarboxylative silylation; heteroarenes silanecarboxylic ... See more keywords