Articles with "silylium type" as a keyword



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Hidden silylium-type reactivity of a siloxane-based phosphonium-hydroborate ion pair.

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Published in 2022 at "Chemical communications"

DOI: 10.1039/d1cc07016a

Abstract: A new class of siloxane-based cations with hidden silylium-type reactivity is provided, which, in combination with an arylborate counteranion, initiates a highly selective para-C(sp2)-F defunctionalization of a perfluorinated aryl group. The hydrodefluorinated aryl borane is… read more here.

Keywords: hidden silylium; siloxane; silylium type; ion pair ... See more keywords