Theoretically predicted divalent silicon(0) compounds: Structures and chemical bonding of silylone in molybdenum pentacarbonyl complexes [Mo(CO)5-Si(XCp∗)2] (X = B–Tl)
Sign Up to like & getrecommendations! Published in 2018 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2018.03.021
Abstract: Abstract Quantum chemical calculations of structures and bonding in the transition metal complexes with silylone ligands [Mo(CO)5-Si(XCp∗)2] (Mo5-SiX) (X = B–Tl) are reported at the BP86 level of theory with various basis sets SVP, TZVPP, TZ2P + . The… read more here.
Keywords: predicted divalent; theoretically predicted; silylone; divalent silicon ... See more keywords
Twisted push-pull disilenes obtained by direct 1,2-hydro/chloroborylation of a silylone.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02160a
Abstract: Overcrowded 1-amino-2-boryldisilenes were isolated as blue crystals by the direct hydro/chloroborylation of a cyclic (alkyl)(amino)silylene-coordinated monatomic silicon complex (silylone) with 9-BBN (BBN = borabicyclo[3.3.1]nonane) hydride/chloride. The extreme twisting and push-pull effect around the SiSi bonds… read more here.
Keywords: direct hydro; silylone; push pull; hydro chloroborylation ... See more keywords