1,2-Silylpyridylation Reaction of Aryl Alkenes with Silylboronate.
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DOI: 10.1021/acs.orglett.2c02074
Abstract: A metal-free silyl-pyridylation of alkenes using silyl boronates and B2pin2 through a pyridine-mediated B-interelement activation has been demonstrated, which provides a practical strategy for a variety of C4-silylalkylated pyridines. DFT calculations and control experiments show… read more here.
Keywords: reaction; reaction aryl; alkenes silylboronate; silylpyridylation reaction ... See more keywords