Articles with "silylsilicates silyl" as a keyword



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Photocatalytic C-Si Bond Formations Using Pentacoordinate Silylsilicates as Silyl Radical Precursors: Synthetic Tricks Using Old Reagents.

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Published in 2023 at "Organic letters"

DOI: 10.1021/acs.orglett.3c00096

Abstract: A visible-light-induced photocatalytic C-Si formation strategy has been disclosed by uncovering the reactivity of Martin's spirosilane-derived pentacoordinate silylsilicates as silyl radical precursors. The hydrosilylation of a broad spectrum of alkenes and alkynes, as well as… read more here.

Keywords: photocatalytic bond; silylsilicates silyl; pentacoordinate silylsilicates; radical precursors ... See more keywords