Low-valent ansa-dimethylsilylene-, dimethylmethylene-bis(cyclopentadienyl) titanium compounds and ansa-titanium–magnesium complexes
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DOI: 10.1016/j.jorganchem.2019.03.003
Abstract: Abstract Reduction of ansa-titanocene dichlorides [X(η5-C5H4)2TiCl2] (X = SiMe2 (1) and CMe2 (2)) in tetrahydrofuran (THF) by preactivated magnesium in the presence of bis(trimethylsilyl)acetylene (BTMSA) yielded complexes [X(η5-C5H4)2Ti(η2-BTMSA)] (X = SiMe2 (3) and CMe2 (4)). The prolonged action of… read more here.
Keywords: sime2 cme2; btmsa; titanium; ansa ... See more keywords