Substitution of Hyp (Hyp = Si(SiMe3)3) at metalloid [Ge9(Hyp)3]- clusters using phosphine stabilized Au(I)Cl.
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DOI: 10.1039/d2dt01665f
Abstract: We present two new intermetalloid cluster compounds [(nBu3P)AuGe9(Hyp)2Au(PnBu3)]2 (1) and [Au(iPr2POC6H4OPiPr2)AuGe9(Hyp)2]2 (2) which are obtained from the reaction of KGe9(Hyp)3 (Hyp = Si(SiMe3)3) with the respective Au(I) phosphine precursors. The products are characterized via X-ray… read more here.
Keywords: substitution hyp; hyp; hyp sime3; hyp hyp ... See more keywords