Rare-earth complexes of the asymmetric amide ligands, N(SiMe3)Ph and N(SiMe3)Cy
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.04.026
Abstract: Abstract Salt metatheses of the rare-earth metal triflates, Ln(OTf)3 (Ln = Sc, Y, La, Ce, Pr, Gd, Dy, Ho, Tb, Lu; OTf = SO3CF3), with KN(SiMe3)Ph in THF generate the Ln[N(SiMe3)Ph]3(THF) complexes which were characterized by X-ray crystallography. All… read more here.
Keywords: sime3; rare earth; sime3 thf; thf complexes ... See more keywords
Trivalent Rare-Earth-Metal Bis(trimethylsilyl)amide Halide Complexes by Targeted Oxidations.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00240
Abstract: In contrast to previously applied salt metathesis protocols the targeted rare-earth-metal compounds Ln[N(SiMe3)2]2(halogenido) were accessed by oxidation of Ln(II) silylamide precursors. Treatment of Sm[N(SiMe3)3]2(thf)2 with 0.5 equiv of C2Cl6 or 0.25 equiv of TeBr4 in… read more here.
Keywords: rare earth; sime3 thf; thf; earth metal ... See more keywords