Photocatalytic cascade alkylation/cyclization of N‐arylacrylamides with simple alkanes: a convenient approach to quaternary C3 alkylated oxindoles
Sign Up to like & getrecommendations! Published in 2024 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202400554
Abstract: A convenient and efficient protocol for the synthesis of 3,3‐dialkylated oxindoles through photocatalytic aerobic radical‐cascade alkylation/cyclization of N‐arylacrylamides with the alkyl radicals generated from simple alkanes is described. This method features a broad substrate scope,… read more here.
Keywords: cyclization arylacrylamides; simple alkanes; alkylation cyclization; cascade alkylation ... See more keywords
Copper-catalyzed radical cascade oxyalkylation of olefinic amides with simple alkanes: highly efficient access to benzoxazines.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc04213b
Abstract: A copper-catalyzed C(sp3)-H bond functionalization of simple alkanes with olefinic amides was developed for the efficient synthesis of important benzoxazine derivatives. It involves new C-C and C-O bond formation in one step via a radical… read more here.
Keywords: radical cascade; catalyzed radical; simple alkanes; copper catalyzed ... See more keywords