Amide-Ligand-Controlled Highly para-Selective Arylation of Monosubstituted Simple Arenes with Arylboronic Acids.
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DOI: 10.1021/jacs.6b12907
Abstract: Pd-catalyzed highly para-selective arylations of monosubstituted simple arenes with arylboronic acids to widely existed biaryls have been developed. Inspired by requisite amide-directing groups in reported selective oxidative couplings, amide ligands, especially DMF, are designed and… read more here.
Keywords: monosubstituted simple; highly para; simple arenes; para selective ... See more keywords