Unique regioselectivity of the Pd-catalysed cross-dehydrogenative coupling reaction of simple polyaromatic hydrocarbons with polyfluoroarenes.
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DOI: 10.1039/d2cc04655e
Abstract: A Pd-catalysed cross-dehydrogenative coupling reaction introduced two polyfluoroarenes into simple polyaromatic hydrocarbons at sterically favourable positions. An investigation of the reaction mechanism revealed that the unique regioselectivity was determined by the reductive elimination step rather… read more here.
Keywords: catalysed cross; reaction; coupling reaction; simple polyaromatic ... See more keywords