Simultaneous Construction of C-N Axial and Central Chirality via Silver-Catalyzed Desymmetrizative [3 + 2] Cycloaddition of Prochiral N-Aryl Maleimides with Activated Isocyanides.
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DOI: 10.1021/acs.orglett.2c01761
Abstract: Herein, we report an unprecedented strategy for the simultaneous construction of a remote C-N stereogenic axis and three contiguous stereogenic carbon centers via silver-catalyzed desymmetrizative [3 + 2] cycloaddition of prochiral N-aryl maleimides with activated… read more here.
Keywords: catalyzed desymmetrizative; simultaneous construction; via silver; silver catalyzed ... See more keywords