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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c09026
Abstract: We present here a new example of chemical reactivity governed by quantum tunneling, which also highlights the limitations of the classical theories. The syn and anti conformers of a triplet 2-formylphenylnitrene, generated in a nitrogen…
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Keywords:
specific reactions;
control;
simultaneous tunneling;
tunneling control ... See more keywords