Articles with "single ion" as a keyword



Lignin Derived Ultrathin All‐Solid Polymer Electrolytes with 3D Single‐Ion Nanofiber Ionic Bridge Framework for High Performance Lithium Batteries

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Published in 2024 at "Advanced Materials"

DOI: 10.1002/adma.202400970

Abstract: The lignin derived ultrathin all‐solid composite polymer electrolyte (CPE) with a thickness of only 13.2 µm, which possess 3D nanofiber ionic bridge networks composed of single‐ion lignin‐based lithium salt (L‐Li) and poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVDF‐HFP) as… read more here.

Keywords: lithium; nanofiber ionic; single ion; ion ... See more keywords

Single‐Ion Conducting Soft Electrolytes for Semi‐Solid Lithium Metal Batteries Enabling Cell Fabrication and Operation under Ambient Conditions

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Published in 2021 at "Advanced Energy Materials"

DOI: 10.1002/aenm.202101813

Abstract: Despite their potential as post lithium‐ion batteries, solid‐state Li‐metal batteries are struggling with insufficient electrochemical sustainability and ambient operation limitations. These challenges mainly stem from lack of reliable solid‐state electrolytes. Here, a new class of… read more here.

Keywords: semi solid; metal batteries; ion conducting; ion ... See more keywords

Phosphine Oxide Coordinated Mononuclear LnIII(Ln = DyIII, ErIII) Single-Ion Magnet with Pseudo-Pentagonal Bipyramidal Geometry.

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Published in 2025 at "ChemPlusChem"

DOI: 10.1002/cplu.202500339

Abstract: Two mononuclear lanthanide complexes, [(L)LnIII(Ph3PO)Cl]·CH3OH] [LnIII = Dy (1) and Er(2)], are isolated employing a pyridine-based ligand, [2,2'-{(1E, 1'E)-pyridine 2,6-diylbis(methaneylylidine}bis(azaneylylidine)diphenol] (H2L) and triphenylphosphine oxide. Both complexes are characterized by single-crystal X-ray diffraction studies. Pseudo-pentagonal bipyramidal… read more here.

Keywords: single ion; pentagonal bipyramidal; pseudo pentagonal; geometry ... See more keywords

Developing Single-ion Conductor Polymer Electrolytes for Rechargeable Magnesium Batteries: A Concept.

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Published in 2025 at "ChemSusChem"

DOI: 10.1002/cssc.202402732

Abstract: Single-ion conductor polymer electrolytes (SICPEs), which exhibit a transference number (tMg2+) approaching unity, offer significant advantages for rechargeable magnesium batteries (RMBs). These advantages include reducing parasitic side reactions from salt anions, promoting the uniform deposition… read more here.

Keywords: polymer electrolytes; rechargeable magnesium; single ion; conductor polymer ... See more keywords

rhOver: Determination of magnetic anisotropy and related properties for dysprosium(III) single‐ion magnets by semiempirical approaches utilizing Hartree–Fock wave functions

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Published in 2018 at "Journal of Computational Chemistry"

DOI: 10.1002/jcc.25565

Abstract: Dysprosium(III) ions are promising candidates for the design of single‐ion magnets (SIMs) as they show an intrinsic strong magnetic anisotropy. However, time‐demanding multireference methods are usually necessary to reproduce low‐lying magnetic states. In this work,… read more here.

Keywords: single ion; magnetic anisotropy; dysprosium iii; anisotropy ... See more keywords

Single-ion gel polymer electrolyte based on in-situ UV irradiation crosslinked polyimide complexed with PEO for lithium-ion batteries.

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Published in 2023 at "Macromolecular rapid communications"

DOI: 10.1002/marc.202200865

Abstract: Lithium-ion batteries (LIBs) have become the research focus of energy storage products. Due to the combination of Li+ and the Lewis basic sites of polymer chains, anions move more than five times faster, which don't… read more here.

Keywords: lithium; lithium ion; single ion; polymer electrolyte ... See more keywords

Creation of a Field-Induced Co(II) Single-Ion Magnet by Doping into a Zn(II) Diamagnetic Metal-Organic Framework.

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Published in 2023 at "Small"

DOI: 10.1002/smll.202301966

Abstract: The combination of single-ion magnets (SIMs) and metal-organic frameworks (MOFs) is expected to produce new quantum materials. The principal issue to be solved in this regard is the development of new strategies for the synthesis… read more here.

Keywords: framework; metal organic; single ion; creation ... See more keywords

Enhancement of electrochemical performance of lithium-ion battery by single-ion conducting polymer addition in ceramic-coated separator

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Published in 2018 at "Journal of Materials Science"

DOI: 10.1007/s10853-018-2353-x

Abstract: AbstractSingle-ion conducting polymers have been widely reported in the literature as solid polymer electrolytes, but their low ionic conductivity has limited industrial applications at ambient temperature. Here, we employed a perfluoroalkyl sulfonamide-based single-ion conducting polymer-lithiated… read more here.

Keywords: separator; single ion; conducting polymer; ion ... See more keywords

Single-ion catalyst of Ni2+ anchored in the interlayer space of layered MnO2 for electro-oxidation of ethanol in alkaline electrolyte

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Published in 2019 at "Electrochemistry Communications"

DOI: 10.1016/j.elecom.2019.106492

Abstract: Abstract A novel catalyst design for electro-oxidation of ethanol is presented, which is featured with the existing state of the catalyst. Specifically, Ni 2+ ions were anchored in the interstitial site of a redox active… read more here.

Keywords: catalyst; oxidation; oxidation ethanol; single ion ... See more keywords

Single Ion Conducting Polymer Electrolytes Based On Versatile Polyurethanes

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Published in 2017 at "Electrochimica Acta"

DOI: 10.1016/j.electacta.2017.04.132

Abstract: Abstract Single-ion polymer electrolytes are expected to play an important role in the development of next-generation lithium metal batteries. In this paper, the synthesis and characterization of single-ion conducting polyurethanes (SIPUs) based on PEG and… read more here.

Keywords: single ion; polymer electrolytes; electrolytes based; ion ... See more keywords

Lithium (4-styrenesulfonyl) (trifluoromethanesulfonyl) imide based single-ion polymer electrolyte with superior battery performance

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Published in 2020 at "Energy Storage Materials"

DOI: 10.1016/j.ensm.2019.06.029

Abstract: Abstract A novel single ion conducting polymer electrolyte is synthesized via a facile and efficient one-step ultraviolet initiated thiol-ene click reaction. The monomers of lithium (4-styrenesulfonyl) (trifluoromethanesulfonyl) imide, pentaerythritol tetrakis (2-mercaptoacetate) and pentaerythritol tetraacrylate are… read more here.

Keywords: polymer electrolyte; lithium; single ion; ion ... See more keywords