From nitrogen inversion in amines to stereoinversion in aminium salts: role of a single water molecule
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DOI: 10.1007/s00214-017-2090-2
Abstract: Contrary to the chiral inversion known in amines (R3N with R being an alkyl group), the stereoinversion in corresponding aminium salts (R3NH+, the protonated amine) is highly unlikely because of a high reaction barrier. A… read more here.
Keywords: inversion; stereoinversion; water molecule; aminium ... See more keywords
Hydrogen release from a single water molecule on Vn+ (3 ≤ n ≤ 30)
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DOI: 10.1038/s42004-020-00396-9
Abstract: Water and its interactions with metals are closely bound up with human life, and the reactivity of metal clusters with water is of fundamental importance for the understanding of hydrogen generation. Here a prominent hydrogen… read more here.
Keywords: hydrogen release; hydrogen; water; water molecule ... See more keywords