Alkene Hydrosilylation on Oxide‐Supported Pt‐Ligand Single‐Site Catalysts
Sign Up to like & getrecommendations! Published in 2019 at "ChemCatChem"
DOI: 10.1002/cctc.201900530
Abstract: Heterogeneous single‐site catalysts (SSCs), widely regarded as promising next‐generation catalysts, blend the easy recovery of traditional heterogeneous catalysts with desired features of homogeneous catalysts: high fraction of active sites and uniform metal centers. We previously… read more here.
Keywords: alkene hydrosilylation; ligand; single site; site catalysts ... See more keywords
Single-atom site catalysts supported on two-dimensional materials for energy applications
Sign Up to like & getrecommendations! Published in 2021 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2021.05.032
Abstract: Abstract Single-atom site catalysts (SACs) and two-dimensional materials (2DM) have gradually become two hot topics in catalysis over the past decades. Their combination with each other can further endow the derived SACs with extraordinary properties… read more here.
Keywords: energy; atom site; dimensional materials; two dimensional ... See more keywords
Iridium Single-Atomic Site Catalysts with Superior Oxygen Reduction Reaction Activity for Sensitive Monitoring of Organophosphorus Pesticides.
Sign Up to like & getrecommendations! Published in 2021 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.1c04665
Abstract: Tremendous efforts have been made in developing single-atomic site catalysts (SASCs) for oxygen reduction reaction (ORR), which is regarded as a pivotal cornerstone in electrochemical energy conversion. However, SASCs for ORR have not been explored… read more here.
Keywords: reduction reaction; oxygen reduction; activity; site catalysts ... See more keywords
Two-Dimensional Fe-N-C Single-Atomic-Site Catalysts with Boosted Peroxidase-Like Activity for a Sensitive Immunoassay.
Sign Up to like & getrecommendations! Published in 2023 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.2c05633
Abstract: Single-atomic-site catalysts (SASCs) with peroxidase (POD)-like activities have been widely used in various sensing platforms, like the enzyme-linked immunosorbent assay (ELISA). Herein, a two-dimensional Fe-N-C-based SASC (2D Fe-SASC) is successfully synthesized with excellent POD-like activity… read more here.
Keywords: two dimensional; site catalysts; like activity; activity ... See more keywords
Directed Structural Transformations of Coordination Polymers Supported Single-Site Cu(II) Catalysts To Control the Site Selectivity of C-H Halogenation.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01891
Abstract: A main difficulty in C-H bond functionalization is to undertake the catalyst control accurately where the reaction takes place. In this work, to achieve highly effective and regioselective single-site catalysts, a three-dimensional (3D) rhombus-like framework… read more here.
Keywords: single site; selectivity; site; structural transformations ... See more keywords
S,O-Functionalized Metal–Organic Frameworks as Heterogeneous Single-Site Catalysts for the Oxidative Alkenylation of Arenes via C–H activation
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c00801
Abstract: Heterogeneous single-site catalysts can combine the precise active site design of organometallic complexes with the efficient recovery of solid catalysts. Based on recent progress on homogeneous th... read more here.
Keywords: functionalized metal; single site; metal organic; heterogeneous single ... See more keywords
Supported Metal Pair-Site Catalysts
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DOI: 10.1021/acscatal.0c02000
Abstract: Complexes with neighboring metal centers in isolated pairs and their analogues on surfaces are drawing increasing attention as catalysts. These include molecular homogeneous catalysts incorporating... read more here.
Keywords: supported metal; metal pair; site catalysts; pair site ... See more keywords
MgO-Supported Iridium Metal Pair-Site Catalysts Are More Active and Resistant to CO Poisoning than Analogous Single-Site Catalysts for Ethylene Hydrogenation and Hydrogen–Deuterium Exchange
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.9b03463
Abstract: Atomically dispersed supported catalysts are drawing wide attention because they offer properties different from those of conventional catalysts, with maximally efficient use of the metals. However... read more here.
Keywords: iridium metal; mgo supported; metal pair; supported iridium ... See more keywords
The Progress and Outlook of Metal Single-Atom-Site Catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c12642
Abstract: Single-atom-site catalysts (SASCs) featuring maximized atom utilization and isolated active sites have progressed tremendously in recent years as a highly prosperous branch of catalysis research. Varieties of SASCs have been developed that show excellent performance… read more here.
Keywords: catalysis; atom site; single atom; site catalysts ... See more keywords
Facile synthesis of precious-metal single-site catalysts using organic solvents
Sign Up to like & getrecommendations! Published in 2020 at "Nature Chemistry"
DOI: 10.1038/s41557-020-0446-z
Abstract: Single-site catalysts can demonstrate high activity and selectivity in many catalytic reactions. The synthesis of these materials by impregnation from strongly oxidizing aqueous solutions or pH-controlled deposition often leads to low metal loadings or a… read more here.
Keywords: metal; facile synthesis; single site; site catalysts ... See more keywords
Electronic structure regulations of single-atom site catalysts and their effects on the electrocatalytic performances
Sign Up to like & getrecommendations! Published in 2021 at "Applied physics reviews"
DOI: 10.1063/5.0048186
Abstract: In recent years, single-atom site catalysts (SACs) have achieved great advancements in heterogeneous and electrochemical catalysis due to the merits of maximal atom utilization, unique electronic and geometric structures, low costs, and high catalytic performances.… read more here.
Keywords: electronic structure; atom site; electrocatalytic performances; structure ... See more keywords