Single-Site Heterogeneous Organometallic Ir Catalysts Embedded on Graphdiyne: Structural Manipulation Beyond the Carbon Support.
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DOI: 10.1002/smll.202203442
Abstract: Accurate control over the coordination circumstances of single-atom catalysts (SACs) is decisive to their intrinsic activity. Here, two single-site heterogeneous organometallic catalysts (SHOCs), Cp*Ir-L/GDY (L = OH- and Cl- ; Cp* = pentamethylcyclopentadienyl), with the… read more here.
Keywords: heterogeneous organometallic; gdy; organometallic catalysts; site heterogeneous ... See more keywords
A Ni/Fe complex incorporated into a covalent organic framework as a single-site heterogeneous catalyst for efficient oxygen evolution reaction
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DOI: 10.1039/d0qi00620c
Abstract: A molecular NiFe complex ([email protected]) was incorporated into the framework of COF (NH4@COF-SO3) by a one-pot post-synthesis method. The use of cyclen that can strongly chelate metal ions enables the formation of completely isolated metal… read more here.
Keywords: site heterogeneous; cof; framework; single site ... See more keywords
Phosphine-based Metal-Organic Layers to Construct Single-Site Heterogeneous Catalyst for Arenes Borylation
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DOI: 10.1039/d3cc01858j
Abstract: Metal-organic layers (MOLs) are highly versatile platforms for creating single-site heterogeneous catalysts. Incorporating molecular functionalities into MOLs is crucial for catalysis. In this study, we designed and synthesized phosphine-containing MOLs... read more here.
Keywords: organic layers; single site; site heterogeneous; metal organic ... See more keywords