Cascade Charge Transitions of Unusually High and Mixed Valence Fe3.5+ in the A-Site Layer-Ordered Double Perovskite SmBaFe2O6.
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DOI: 10.1021/jacs.3c01654
Abstract: The A-site layer-ordered double perovskite SmBaFe2O6 was obtained by topochemical of oxidizing A-site layer-ordered SmBaFe2O5 in ozone at a low temperature. The compound contained unusually high and mixed valence Fe3.5+ and was found to show… read more here.
Keywords: layer ordered; site layer; charge; ordered double ... See more keywords