Photo-Induced Construction and Recovery of Cu+ Sites in Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202302885
Abstract: The adjustment of the valence state of metal ions is crucial for various applications because peculiar activity originates from metal ions with specific valence. Cu+ can interact with molecules possessing unsaturated bonds like CO via… read more here.
Keywords: sites metal; organic frameworks; photo induced; metal organic ... See more keywords
Open Metal Sites in the Metal–Organic Framework CPO-27-Cu: Detection of Regular and Defect Copper Species by CO and NO Probe Molecules
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.8b04045
Abstract: The open copper metal sites in CPO-27-Cu were studied by means of IR spectroscopy of adsorbed CO and NO, and density functional theory calculations. Very low Lewis acidity of the Cu2+ sites was established by… read more here.
Keywords: open metal; metal organic; copper; sites metal ... See more keywords
Unraveling the Reaction Mechanism and Active Sites of Metal–Organic Frameworks for Glucose Transformations in Water: Experimental and Theoretical Studies
Sign Up to like & getrecommendations! Published in 2020 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.0c04398
Abstract: The catalytic performance of two different MOFs, UiO-66 and MOF-808, containing Lewis acid active sites has been evaluated for the transformation of glucose in water and compared with that of analo... read more here.
Keywords: active sites; mechanism active; unraveling reaction; water ... See more keywords
Structure-Activity Relationship Insights for Organophosphonate Hydrolysis at Ti(IV) Active Sites in Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c13887
Abstract: Organophosphorus nerve agents are among the most toxic chemicals known and remain threats to humans due to their continued use despite international bans. Metal-organic frameworks (MOFs) have emerged as a class of heterogeneous catalysts with… read more here.
Keywords: active sites; structure activity; sites metal; organic frameworks ... See more keywords