{Ti6}/{Ti10} Wheel Cluster Substituted Silicotungstate Aggregates.
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DOI: 10.1021/acs.inorgchem.1c02788
Abstract: Two novel Ti-oxo wheel cluster substituted silicotungstates (STs) [H2N(CH3)2]9H9[Ti6O6(SiW10O37)3]·11H2O (1) and [H2N(CH3)2]16H10[Ti10O11(SiW10O37)2(SiW9O35)2]·14H2O (2) have been made by hydrothermal reactions. The polyoxoanion of 1 is a ring-shaped trimer where a Ti6O6 ({Ti6}) wheel cluster is encapsulated… read more here.
Keywords: siw10o37; wheel cluster; chemistry; cluster substituted ... See more keywords