Six-coordinate nitrosyl complex of Co-meso-tetra-p-tolylporphyrin with a trans-1-methylimidazole ligand
Sign Up to like & getrecommendations! Published in 2017 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-017-1870-0
Abstract: Electron absorption and Fourier-transform IR spectroscopy was used to determine that the reaction of 1-methylimidazole (1-MeIm) with a nitrosyl complex of meso-tetra-p-tolylporphyrinate cobalt (Co(TTP)(NO)) at 210—240 K led to the formation of the six-coordinate complex… read more here.
Keywords: complex meso; methylimidazole ligand; meso tetra; six coordinate ... See more keywords
Six coordinate capped trigonal bipyramidal complexes
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DOI: 10.1016/j.ccr.2017.06.019
Abstract: Abstract This review collects the examples of a rare, six-coordinate geometry, the capped trigonal bipyramid (CTB). Examples have been identified for d 0 Sc(III), Y(III), Zr(IV), Ta(V), d 4 Mo(II), d 2 Mo(IV) and W(IV),… read more here.
Keywords: coordinate capped; capped trigonal; trigonal bipyramidal; six coordinate ... See more keywords
Coligand Effects on the Field-Induced Double Slow Magnetic Relaxation in Six-Coordinate Cobalt(II) Single-Ion Magnets (SIMs) with Positive Magnetic Anisotropy.
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DOI: 10.1021/acs.inorgchem.9b01719
Abstract: Two mononuclear cobalt(II) compounds of formula [Co(dmphen)2(OOCPh)]ClO4·1/2H2O·1/2CH3OH (1) and [Co(dmbipy)2(OOCPh)]ClO4 (2) (dmphen = 2,9-dimethyl-1,10-phenanthroline, dmbipy = 6,6'-dimethyl-2,2'-bipyridine and HOOCPh = benzoic acid) are prepared and magnetostructurally investigated. Each cobalt(II) ion is six-coordinate with a distorted… read more here.
Keywords: relaxation; cobalt; field; six coordinate ... See more keywords
Stereoisomeric coordination polymers based on facial and meridional six-coordinate dysprosium(III ).
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00334a
Abstract: Due to the small differences in the chemical properties of facial (fac) and meridional (mer) stereoisomers, selective synthesis of one of the isomers is challenging, especially for lanthanide complexes. By using a flexible bidentate phosphine… read more here.
Keywords: mer; coordination; six coordinate; iii ... See more keywords