Making Heterometallic Metal-Metal Bonds in Keggin-Type Polyoxometalates by a Six-Electron Reduction Process.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03769
Abstract: Polyoxometalates (POMs) represent a promising class of molecular electron reservoirs. However, their multielectron reduction gives rise to intricate physical-chemical phenomena that must be fully understood for their future use in energy-storage devices. Herein, we show… read more here.
Keywords: keggin type; metal bonds; six electron; metal ... See more keywords
Activating sulfur oxidation reaction via six-electron redox mesocrystal NiS2 for sulfur-based aqueous batteries
Sign Up to like & getrecommendations! Published in 2022 at "National Science Review"
DOI: 10.1093/nsr/nwac268
Abstract: ABSTRACT Sulfur-based aqueous batteries (SABs) are deemed promising candidates for safe, low-cost, and high-capacity energy storage. However, despite their high theoretical capacity, achieving high reversible value remains a great challenge due to the thermodynamic and… read more here.
Keywords: reaction; based aqueous; sulfur; aqueous batteries ... See more keywords