Single-Step Access to Thiolate-Supported, Six-Iron Clusters with an Authentic Carbide: Synthesis of [Fe6(μ6-C)(μ2-Stol)(μ2-CO)2(CO)12]3 via Non-PSEPT, Redox Intermediates.
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DOI: 10.1021/acs.inorgchem.4c05362
Abstract: We report a general synthetic method to access iron-carbide(carbonyl) clusters ligated by thiolate. We previously established that multiple neutral ligand substitution (phosphine) was enabled by utilizing the conventional six-iron carbide cluster [Fe6(μ6-C)(μ2-CO)4(CO)12]2- and generating the… read more here.
Keywords: thiolate; iron; six iron; fe6 ... See more keywords