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Catalytic Asymmetric Construction of a 1,2,4-Benzotriazepine Skeleton via Diastereo- and Enantioselective Decarboxylative [4 + 3] Cyclization.

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Published in 2021 at "Organic letters"

DOI: 10.1021/acs.orglett.1c00073

Abstract: We have developed a protocol for palladium-catalyzed decarboxylative [4 + 3] cycloaddition reactions between 4-vinyl benzoxazinanones and azomethine imines to generate moderate to good yields of structurally diverse 1,2,4-benzotriazepines bearing two stereogenic centers with good… read more here.

Keywords: asymmetric construction; skeleton; construction benzotriazepine; benzotriazepine skeleton ... See more keywords