Vibrational analysis of a rate-slowing conformational kinetic isotope effect
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DOI: 10.1016/j.tet.2018.12.051
Abstract: Abstract An enthalpy-entropy approach to analyzing a rate-slowing conformational kinetic isotope effect (CKIE) in a deuterated doubly-bridged biaryl system is described. The computed isotope effect (kH/kD = 1.075, 368 K) agrees well with the measured value (kH/kD = 1.06, 368 K).… read more here.
Keywords: isotope; rate slowing; isotope effect; slowing conformational ... See more keywords