Accessing Unusual Reactivity through Chelation-Promoted Bond Weakening.
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DOI: 10.1021/acs.inorgchem.3c00298
Abstract: Highly reducing Sm(II) reductants and protic ligands were used as a platform to ascertain the relationship between low-valent metal-protic ligand affinity and degree of ligand X–H bond weakening with the goal of forming potent proton-coupled… read more here.
Keywords: bond weakening; ligand; smbr2 nmea; unusual reactivity ... See more keywords