Synthetic studies toward longeracemine: a SmI2-mediated spirocyclization and rearrangement cascade to construct the 2-azabicyclo[2.2.1]heptane frameworkâ
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DOI: 10.1039/d0sc03422c
Abstract: Longeracemine, a member of the Daphniphyllum family of alkaloids contains a novel carbon framework featuring a highly functionalized 2-azabicyclo[2.2.1]heptane core as part of an overall 5/6/5/5/6/5 skeleton. A synthetic intermediate containing the core of longeracemine… read more here.
Keywords: framework; synthetic studies; azabicyclo heptane; smi2 mediated ... See more keywords