Windmill-like Ln4 Clusters [Ln = Tb(III) and Dy(III)] Bridged by [α-AsW9O33]9- Unit Showing Zero-Field SMM Behavior: Experimental and Theoretical Investigation.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02298
Abstract: Herein, two polyoxometalate (POM)-ligated tetranuclear rare-earth metal complexes having the molecular formula [CsxK24-x{Ln4(H2O)8(α-AsW9O33)4}]·yH2O {x = 5, y = 20, and Ln = Tb(III) (1); and x = 6, y = 28, and Ln = Dy(III)… read more here.
Keywords: experimental theoretical; process; smm behavior; iii iii ... See more keywords
Systematic studies of hexanuclear {MIII4LnIII2} complexes (M = Fe, Ga; Ln = Er, Ho): structures, magnetic properties and SMM behavior
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry frontiers"
DOI: 10.1039/c7qi00091j
Abstract: Four isostructural MIII4LnIII2 coordination clusters, [M4Ln2(μ3-OH)2(nbdea)4(C6H5COO)8]·MeCN (M = Fe, Ln = Er (1); M = Ga, Ln = Er (2); M = Fe, Ln = Ho (3); M = Ga, Ln = Ho (4)) have… read more here.
Keywords: studies hexanuclear; miii4lniii2 complexes; smm behavior; systematic studies ... See more keywords
Exploration of SMM behavior of Ln2 complexes derived from thianaphthene-2-carboxylic acid.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01984g
Abstract: Two lanthanide-based dinuclear complexes [LnIII(L)3(DMF)(H2O)]2 (Ln = DyIII (1)/TbIII (2)) derived from thianaphthene-2-carboxylic acid have been synthesized and characterized in detail. Single-crystal XRD analyses confirm that the centro-symmetric discrete dimeric structures contain eight-coordinated lanthanide centers… read more here.
Keywords: smm behavior; carboxylic acid; derived thianaphthene; exploration smm ... See more keywords