A dinuclear Co(III)/Co(II) complex based on the H2pmide ligand showing field-induced SMM behaviour.
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DOI: 10.1039/d2dt03492a
Abstract: We report the synthesis, structural characterization and SMM behaviour of a new mixed valence Co(II)/Co(III) dinuclear complex bearing the H2pmide ligand. Well defined molecule pairs are observed in the crystal structure, bound through H-bond interactions… read more here.
Keywords: field induced; induced smm; smm behaviour; field ... See more keywords
Synthesis, X-ray structure and magnetic properties of the apically functionalized monocapped cobalt(II) tris-pyridineoximates possessing SMM behaviour.
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DOI: 10.1039/d2dt04073e
Abstract: The title cobalt(II) pseudoclathrochelate complexes possess an intermediate trigonal prismatic-trigonal antiprismatic geometry. As follows from PPMS data, they exhibit an SMM behaviour with Orbach relaxation barriers of approximately 90 K. Paramagnetic NMR experiments confirmed a… read more here.
Keywords: magnetic properties; structure magnetic; synthesis ray; smm behaviour ... See more keywords