Redox and structural controls on tin isotopic fractionations among magmas
Sign Up to like & getrecommendations! Published in 2020 at "Geochimica et Cosmochimica Acta"
DOI: 10.1016/j.gca.2019.09.036
Abstract: Abstract Recent analytical developments have made possible the determination of the isotopic composition of tin in igneous rocks. In order to establish a framework to interpret the mass-dependent tin isotopic signatures of planetary materials, seven… read more here.
Keywords: sn2; isotope; tin isotopic; chemistry ... See more keywords
Towards less hazardous industrial compounds: coupling quantum mechanical computations, biomarker responses and behavioral profiles identify bioactivity of SN2 electrophiles in alternative vertebrate models.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical research in toxicology"
DOI: 10.1021/acs.chemrestox.9b00290
Abstract: Sustainable molecular design of less hazardous chemicals promises to reduce risks to public health and the environment. Computational chemistry modeling coupled with alternative toxicology models (e.g., larval fish) present unique high-throughput opportunities to understand structural… read more here.
Keywords: sn2; sn2 electrophiles; alternative vertebrate; less hazardous ... See more keywords
Exploring Mechanisms of Biotic Chlorinated Alkane Reduction: Evidence of Nucleophilic Substitution (SN2) with Vitamin B12.
Sign Up to like & getrecommendations! Published in 2022 at "Environmental science & technology"
DOI: 10.1021/acs.est.1c06066
Abstract: Chlorinated alkanes are notorious groundwater contaminants. Their natural reductive dechlorination by microorganisms involves reductive dehalogenases (RDases) containing cobamide as a cofactor. However, underlying mechanisms of reductive dehalogenation have remained uncertain. Here, observed products, radical trap… read more here.
Keywords: cobalamin; sn2; nucleophilic substitution; substitution sn2 ... See more keywords
Highly Selective and Sensitive Ratiometric Detection of Sn2+ Ions Using NIR-Excited Rhodamine-B-Linked Upconversion Nanophosphors
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c02671
Abstract: Detection of Sn2+ ions in environmental and biological samples is essential owing to the toxicological risk posed by excess use tin worldwide. Herein, we have designed a nanoprobe involving upconversion nanophosphors linked with a rhodamine-based… read more here.
Keywords: upconversion nanophosphors; sn2; detection sn2; nir excited ... See more keywords
An ICT-based fluorescence enhancement probe for detection of Sn2+ in cancer cells
Sign Up to like & getrecommendations! Published in 2020 at "RSC Advances"
DOI: 10.1039/d0ra07330j
Abstract: Development of a novel fluorescence enhancement probe for detection of Sn2+ in organisms, with high selectivity and sensitivity, is of great interest but remains a great challenge. Herein, an ICT-based fluorescence probe TPPB was rationally… read more here.
Keywords: detection; probe; sn2; fluorescence ... See more keywords
Unique regulation of Na‐glutamine cotransporter SN2/SNAT5 in rabbit intestinal crypt cells during chronic enteritis
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Cellular and Molecular Medicine"
DOI: 10.1111/jcmm.13257
Abstract: The only Na‐nutrient cotransporter described in mammalian small intestinal crypt cells is SN2/SNAT5, which facilitates glutamine uptake. In a rabbit model of chronic intestinal inflammation, SN2 stimulation is secondary to an increase in affinity of… read more here.
Keywords: sn2; stimulation; crypt cells; cotransporter ... See more keywords
Computational Studies of Coinage Metal Anion M− + CH3X (X = F, Cl, Br, I) Reactions in Gas Phase
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27010307
Abstract: We characterized the stationary points along the nucleophilic substitution (SN2), oxidative insertion (OI), halogen abstraction (XA), and proton transfer (PT) product channels of M− + CH3X (M = Cu, Ag, Au; X = F, Cl,… read more here.
Keywords: halogen; gas phase; sn2; ch3x reactions ... See more keywords