Copper-Mediated SN2' Allyl-Alkyl and Allyl-Boryl Couplings of Vinyl Cyclic Carbonates.
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DOI: 10.1021/acs.orglett.7b02947
Abstract: A method for the copper-catalyzed borylmethylation and borylation of vinyl cyclic carbonates through an SN2' mechanism is reported. These singular reactions involve selective SN2' allylic substitutions with concomitant ring opening of the cyclic carbonate and… read more here.
Keywords: copper mediated; sn2 allyl; mediated sn2; allyl ... See more keywords